Supercalifragilisticexpialidocious, which turns out to be the 5th largest English word. I had heard of the 4th largest (Pneumonoultramicroscopicsilicovolcanoconiosis), but the only thing I could remember was that it had the word volcano in it.
Ambystoma-mexicanum is the latin name for the cute little bugger in my avatar. I breed that species so that's the longest word I'd be likely to use in a normal everyday conversation.
The longest word I know would be the one mentioned above from wikipedia (I really don't feel like typing it out though)
Donaudampfschifffahrtselektrizitätenhauptbetriebswerkbauunterbeamtengesellschaft. That's what I get for liking German people. They spam me with long words as a long-running joke. I don't know what it means, and I don't intend to find out.
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"Democracy is the road to socialism." -Karl Marx "The goal of socialism is communism." -Vladimir Lenin