I'd probably kill that guy from last year with all that Rapture sh!t. Seriously, because of him, hundreds of thousands of people either gave up EVERYTHING they own, or even commit suicide. And his punishment? He got paid millions by his supporters.
Either that, or I'd kill a zombie. Zombies are bad.
I'd find someone who committed a murder and make sure he/she would be a person who would not be missed.
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"For I am a sinner in the hands of an angry God. Bloody Mary, full of vodka, blessed are you among cocktails. Pray for me now and at the hour of my death, which I hope is soon. Amen." - Sterling Archer, aka "Duchess", aka "world's most dangerous spy".
If I had a get out of jail free card then I would defiantly kill someone who either wanted to die, or just acted like a major douche (the second one is far from true, although I wish it weren't).
Otherwise, I'd have to find some lonely old man who has no family, no friends, no hospice nurse checking on him, and no one to notice he's gone. Then I'd have to drag him into the woods with about half a kilogram of termite and burn his body until only ash remained. >: )