I'd say the beacon, as the nether star requires getting wither skeleton heads, which are rather tedious to get. Ghasts, on the other hand show up all the time so it is just a matter of having a small base of cobblestone and a lot of arrows.
Dragon Egg. You need blazes, and a bunch of endermen, then good gear, then travel very far, then make more if some ender eyes broke along the way, then remember to bring a piston and blocks, and fight the Enderdragon, and it’s very hard.
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lol/Rant/Whatever of the…!: Beyond: Two Souls is a sad/depressing game. Not like the ending of Mother 3 isn’t more sad.
Emeralds, simply because of how rare they are. I've never seen one.
You can get unlimited emeralds from villagers (have to trade back to open up locked trades) and from chests in desert/jungle temples; otherwise, you need to find an Extreme Hills biome, where they can be more common than diamonds, if scattered over a larger range and in veins of one (I find plenty in caves); they average about 15 times rarer than diamonds overall, maybe different in 1.7.2.
That said, I've killed the Ender Dragon several times but have never gotten even one Wither skeleton skull, and in turn a Nether star to make a beacon, so I'd say beacon by a long shot (I have killed the Wither by making one in Creative and then going to Survival, pretty easy if you do it right, but I'm talking about plain Survival).
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Right now I would say Wither because I am trying to defeat one in a SSP let's play series I am doing on my youtube channel and I can't seem to find wither skeletons. Past that I would say a charged creeper...it requires way to much luck!
For me the hardest to obtain and most rewardable item to he has to be Endstone because of the server I play on. Endstone has the highest IGM(in game money) to block ratio. The next most profitable item being Nether Quartz Blocks.