Looks like were on the same page
PDF export is a good idea, i do so love PDF. But export to PNG might also be good, adding the exported PNGs together in something like gimp then drawing arrows and adding notes to make blueprints with instructions is something sorely needed in the community I think.
I don't know much about save formats, but the options I think would be useful for saving/exporting the design:
1) a format the app can read again, something small so it can be emailed and shared easily and continued editing.
2) printable format, PDF, colour and back/white with symbolic legend for cheap printing maybe.
3) graphic format, PNG, for display on the forums, making detailed long multi-part mega structure instructions.
The textures I would like is every placeable block

Nether blocks, logs, glass (skip the transparency for now, i don't need to see through the glass, just need to know that it is there

), some unplacebles as well, leaves specifically, just to be able to add a tree to the design to indicate "plant the thing here, and hope it grows", and tree houses are all the rage the last few weeks. Furnace, chest and workbench need some love to, and don't need to be true to minecraft, using the same texture on all sides is exceptable.
Half blocks and stairs are needed as well, they are used in most designs. Doors don't need the transparency, just like the glass, but I don't know how difficult the no cube parts are to add
Viaduct will be awesome, if I can adjust the amount of supports, the height and thickness of the arches, amount of arches parallel to each other and the distance in between. Torus needs inner radius, outer radius, height above center line, height below. Speaking of height below and above the center line, it would be nice for the 'sphere' shape as well, make eggs en UFO shaped buildings

. Spirals are a big one to! Just thought of that, what else is difficult to make in minecraft, hmmm, a face shape generator if you are really bored haha, perfect easter island head finally
Tools for freeform like line, fill, ellips, square, figure 8, triangle, zigzag, are always fun, but I wonder if I would actually use them, but I guess adding the standard set of tools is needed.
Lastly the 3D view, changing the view direction would be nice, even if it is only the 4 views, one from each corner.
Can't wait for an update