A PRETTY annoying NPC is the rebels in HL2. "It's Freeman, let's follow him!" Okay just don't get in my wa- *Thin hallway* "Let me get out of your way." AND THEY SHUFFLE AROUND WITH THE FELLOW REBELS, TRYING TO MOVE. Why I wish there was friendly fire.
It's valuable, but he seems to be determined to commit suicide on the way there.
Which is why they give you the option to save him. Story-wise, it's because he isn't all that great of a pilot.
Most annoying NPC ever is not Navi, while she can be a little annoying, she gives you enemy details! I would have to say that the most annoying NPC ever would be....any NPC that thinks it's their duty to block off the player from interesting areas until late into the game.
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I scored 100% on the Minecraft Trivia Quiz. How much do you know about Minecraft? TOPICS I MAKE, Y U NO STAY ALIVE?